ASTM-D5453 2008

$40.63

D5453-08a Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence

Published By	Publication Date	Number of Pages
ASTM	2008	10

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Description

ASTM D5453-08a

Historical Standard: Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence

ASTM D5453

Scope

1.1 This test method covers the determination of total sulfur in liquid hydrocarbons, boiling in the range from approximately 25 to 400°C, with viscosities between approximately 0.2 and 20 cSt (mm²/S) at room temperature.

1.2 Three separate interlaboratory studies (ILS) on precision, and three other investigations that resulted in an ASTM research report, have determined that this test method is applicable to naphthas, distillates, engine oil, ethanol, Fatty Acid Methyl Ester (FAME), and engine fuel such as gasoline, oxygen enriched gasoline (ethanol blends, E-85, M-85, RFG), diesel, biodiesel, diesel/biodiesel blends, and jet fuel. Samples containing 1.0 to 8000 mg/kg total sulfur can be analyzed (Note 1).

Note 1—Estimates of the pooled limit of quantification (PLOQ) for the precision studies were calculated. Values ranged between less than 1.0 and less than 5.0 mg/kg (see Section 8 and 15.1).

1.3 This test method is applicable for total sulfur determination in liquid hydrocarbons containing less than 0.35 % (m/m) halogen(s).

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For warning statements, see 3.1, 6.3, 6.4, Section 7, and 8.1.

Keywords

analysis; biodiesel; biodiesel-fuel blends; E-85; ethanol; ethanol-fuel blends; diesel; fluorescence; gasoline; jet fuel; kerosine; M-85; RFG; sulfur; ultraviolet; Contamination–petroleum products; Fluorescence–petroleum products; Fuel sulfur; Process feeds; Purity analysis–petroleum products; Total sulfur content; Ultraviolet (UV) analysis–petroleum products

ICS Code

ICS Number Code 75.100 (Lubricants, industrial oils and related products)

DOI: 10.1520/D5453-08A

PDF Catalog

PDF Pages	PDF Title
1	Scope Referenced Documents Summary of Test Method
2	Significance and Use Apparatus FIG. 1
3	Reagents FIG. 2
4	Hazards Sampling Preparation of Apparatus Calibration and Standardization FIG. 3
5	TABLE 1 TABLE 2
6	Procedure Calculation Report Quality Control Precision and Bias
7	Keywords X1. QUALITY CONTROL X1.1 X1.2 X1.3 X1.4 X1.5 TABLE 3
8	X2. IMPORTANT FACTORS IN DIRECT INJECTION ANALYSIS OF HYDROCARBONS USING TEST METHOD D 5453 (SULFUR) X2.1 Furnace Temperature X2.2 Needle Tip Position during Injection X2.3 Injection Peak/Needle Blank X2.4 Residence Time of Needle in Furnace X2.5 Injection Size X2.6 Injection Rate and Frequency X2.7 Flow Path, Leak Check, and Back Pressure X2.8 Gas Flow Settings X2.9 Membrane Dryer Purge X2.10 Sample Homogeneity/Calibration Response X2.11 Baseline Stability X2.12 Calibration Materials/ Standard Curve Construction TABLE X2.1
9	X3. IMPORTANT FACTORS IN BOAT-INLET ANALYSIS OF HYDROCARBONS USING TEST METHOD D 5453 (SULFUR) X3.1 Furnace Temperature X3.2 Boat Path X3.3 Boat Entry Rate and Residence Time of Sample in Furnace X3.4 Injection Size X3.5 Injection Rate and Frequency X3.6 Boat Temperature at Time of Sample Introduction X3.7 Sample Flow Path: Leak Check and Back Pressure X3.8 Gas Flow Settings X3.9 Membrane Dryer Purge X3.10 Sample Homogeneity/Calibration Response X3.11 Boat Blank/Baseline Stability X3.12 Calibration Materials/ Standard Curve Construction TABLE X3.1

Additional information

Standard Title	D5453-08a Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence
Published Code	ASTM
Publication Date	2008
Pages Count	10